Revision notes · Bonding, structure, and the properties of matter

Bulk and surface properties of matter including nanoparticles

Sizes of particles and their properties4.2.4.1

Definition: A nanoparticle is a particle with a diameter between 1 and 100 nanometres, consisting of a few hundred atoms.

Nanoparticles are extremely tiny particles that behave differently from bulk materials because of their very high surface area to volume ratio.

TypeDiameter
Nanoparticles1–100 nm (1 × 10⁻⁹ m to 1 × 10⁻⁷ m)
Fine particles100–2,500 nm
Coarse particles (dust)2,500–10,000 nm
  • As the side length of a cube decreases by a factor of 10, its surface area to volume ratio increases by a factor of 10.
  • Their huge surface area to volume ratio means much smaller quantities of nanoparticles are needed to achieve the same effect as bulk materials.
⚠️ Common mistake: Thinking nanoparticles are individual atoms or molecules, rather than structures made of a few hundred atoms.
🧠 Remember: Shrink the side length by 10, and the surface area to volume ratio jumps by 10.

Uses of nanoparticles4.2.4.2

Definition: Nanoscience is the study and application of structures that are between 1 and 100 nanometres in size.

The unique properties of nanoparticles give them many practical applications in medicine, consumer products, and industrial catalysts.

UseHow
CatalystsMassive surface area provides many active sites for reactions
SunscreensTitanium dioxide nanoparticles give UV protection without a visible white residue
Antibacterial productsSilver nanoparticles in deodorants, wound dressings, clothing
MedicineCage-like nanoparticles deliver drugs directly to target cells (e.g. tumours)
  • The risks of nanoparticles are not fully understood, as they could enter human body cells or cause long-term environmental damage.
⚠️ Common mistake: Assuming nanoparticles are completely safe because they are used in everyday products; their long-term health and environmental effects are still unknown.
🧠 Remember: Think MEDIC: Medicine, Electronics, Deodorants, Industrial catalysts, Cosmetics/sunscreens.

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