Revision notes · Chemical changes
Reactivity of metals
Metal oxides4.4.1.1
Definition: Oxidation is a chemical reaction in which a substance gains oxygen.
Metals react with oxygen to form metal oxides in oxidation reactions.
- •Metals react with oxygen to produce metal oxides.
- •The gain of oxygen by an element or compound is called oxidation.
- •The loss of oxygen from a compound is called reduction.
- •When magnesium reacts with oxygen, magnesium is oxidised to form magnesium oxide.
⚠️ Common mistake: Confusing oxidation (gaining oxygen) with reduction (losing oxygen).
🧠 Remember: Gain oxygen = Oxidation; Loss of oxygen = Reduction.
The reactivity series4.4.1.2
Definition: The reactivity series is an arrangement of metals in order of their reactivity, from most reactive to least reactive.
A metal's reactivity depends on its tendency to lose electrons and form positive ions.
- •Metals lose electrons to form positive ions when they react.
- •A more reactive metal will displace a less reactive metal from its compound in a solution.
- •Potassium, sodium, and lithium react violently with water, whereas metals like zinc and iron react with dilute acids.
- •Carbon and hydrogen are non-metals included in the reactivity series as reference points: carbon shows which metals can be extracted by reduction with carbon, and hydrogen shows which metals will react with dilute acids.
⚠️ Common mistake: Thinking unreactive metals like gold or silver react with dilute acids to produce hydrogen gas.
🧠 Remember: Please Stop Like Calling Me A Cute Zebra – Potassium, Sodium, Lithium, Calcium, Magnesium, Aluminium, Carbon, Zinc.
Extraction of metals and reduction4.4.1.3
Definition: Metal extraction is the process of obtaining a pure metal from its naturally occurring ore.
Unreactive metals are found in native form, while most metals must be extracted from their ores by reduction.
- •Unreactive metals such as gold are found as native metals directly in the Earth's crust.
- •Metals less reactive than carbon can be extracted from their oxides by reduction with carbon.
- •During reduction with carbon, carbon gains oxygen (is oxidised) and the metal oxide loses oxygen (is reduced).
- •Metals more reactive than carbon must be extracted using electrolysis.
⚠️ Common mistake: Assuming carbon can extract all metals from their ores, including those above carbon like aluminium.
🧠 Remember: Below carbon = reduce with carbon; Above carbon = extract using electrolysis.
Oxidation and reduction in terms of electrons4.4.1.4
Definition: Oxidation is the loss of electrons, and reduction is the gain of electrons.
Redox reactions involve the transfer of electrons between reacting species.
- •Oxidation occurs when an atom or ion loses electrons.
- •Reduction occurs when an atom or ion gains electrons.
- •Displacement reactions are redox reactions because one species is oxidised while another is reduced.
- •Ionic equations show electron transfer and omit spectator ions that do not change during the reaction.
⚠️ Common mistake: Forgetting that oxidation and reduction occur simultaneously in a redox reaction.
🧠 Remember: OIL RIG – Oxidation Is Loss, Reduction Is Gain (of electrons).
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