Revision notes · Chemical changes

Reactivity of metals

Metal oxides4.4.1.1

Definition: Oxidation is a chemical reaction in which a substance gains oxygen.

Metals react with oxygen to form metal oxides in oxidation reactions.

  • Metals react with oxygen to produce metal oxides.
  • The gain of oxygen by an element or compound is called oxidation.
  • The loss of oxygen from a compound is called reduction.
  • When magnesium reacts with oxygen, magnesium is oxidised to form magnesium oxide.
⚠️ Common mistake: Confusing oxidation (gaining oxygen) with reduction (losing oxygen).
🧠 Remember: Gain oxygen = Oxidation; Loss of oxygen = Reduction.

The reactivity series4.4.1.2

Definition: The reactivity series is an arrangement of metals in order of their reactivity, from most reactive to least reactive.

A metal's reactivity depends on its tendency to lose electrons and form positive ions.

Reactivity series
  • Metals lose electrons to form positive ions when they react.
  • A more reactive metal will displace a less reactive metal from its compound in a solution.
  • Potassium, sodium, and lithium react violently with water, whereas metals like zinc and iron react with dilute acids.
  • Carbon and hydrogen are non-metals included in the reactivity series as reference points: carbon shows which metals can be extracted by reduction with carbon, and hydrogen shows which metals will react with dilute acids.
⚠️ Common mistake: Thinking unreactive metals like gold or silver react with dilute acids to produce hydrogen gas.
🧠 Remember: Please Stop Like Calling Me A Cute Zebra – Potassium, Sodium, Lithium, Calcium, Magnesium, Aluminium, Carbon, Zinc.

Extraction of metals and reduction4.4.1.3

Definition: Metal extraction is the process of obtaining a pure metal from its naturally occurring ore.

Unreactive metals are found in native form, while most metals must be extracted from their ores by reduction.

  • Unreactive metals such as gold are found as native metals directly in the Earth's crust.
  • Metals less reactive than carbon can be extracted from their oxides by reduction with carbon.
  • During reduction with carbon, carbon gains oxygen (is oxidised) and the metal oxide loses oxygen (is reduced).
  • Metals more reactive than carbon must be extracted using electrolysis.
⚠️ Common mistake: Assuming carbon can extract all metals from their ores, including those above carbon like aluminium.
🧠 Remember: Below carbon = reduce with carbon; Above carbon = extract using electrolysis.

Oxidation and reduction in terms of electrons4.4.1.4

Definition: Oxidation is the loss of electrons, and reduction is the gain of electrons.

Redox reactions involve the transfer of electrons between reacting species.

  • Oxidation occurs when an atom or ion loses electrons.
  • Reduction occurs when an atom or ion gains electrons.
  • Displacement reactions are redox reactions because one species is oxidised while another is reduced.
  • Ionic equations show electron transfer and omit spectator ions that do not change during the reaction.
⚠️ Common mistake: Forgetting that oxidation and reduction occur simultaneously in a redox reaction.
🧠 Remember: OIL RIGOxidation Is Loss, Reduction Is Gain (of electrons).

Feel like you’ve got it?

Practise it now →