Revision notes · Chemical analysis
Identification of common gases
Test for hydrogen4.8.2.1
The test for hydrogen uses a lit flame to produce a distinctive sound.
- •Hold a burning splint near the open end of a test tube containing the gas.
- •If hydrogen is present, it burns rapidly with a characteristic 'squeaky pop' sound.
- •The squeaky pop sound is caused by hydrogen reacting rapidly with oxygen to form water.
⚠️ Common mistake: Using a glowing splint instead of a burning splint with an open flame.
🧠 Remember: Hydrogen pops with a lit flame!
Test for oxygen4.8.2.2
The test for oxygen uses an embers-only splint to demonstrate combustion.
- •Light a wooden splint and blow it out so it is only glowing at the tip.
- •Insert the glowing splint into a test tube containing the gas sample.
- •If oxygen is present, the glowing splint relights into a flame.
⚠️ Common mistake: Using a burning splint with an active flame rather than a glowing splint.
🧠 Remember: Oxygen relights a glowing splint!
Test for carbon dioxide4.8.2.3
Definition: Limewater is an aqueous solution of calcium hydroxide used as a chemical indicator for carbon dioxide.
The test for carbon dioxide uses calcium hydroxide solution to form a precipitate.
- •Bubble the gas sample through or shake it with an aqueous solution of limewater.
- •If carbon dioxide is present, the limewater turns cloudy (or milky).
- •The cloudy appearance is due to the formation of a fine white precipitate of insoluble calcium carbonate.
⚠️ Common mistake: Saying limewater turns clear when it actually starts clear/colourless and turns cloudy.
🧠 Remember: CO2 turns limewater cloudy!
Test for chlorine4.8.2.4
The test for chlorine relies on its strong bleaching properties.
- •Place a piece of damp litmus paper into the test tube containing the gas.
- •If chlorine is present, the litmus paper is bleached and turns white.
- •The litmus paper may turn red briefly before bleaching because chlorine forms an acidic solution with water.
⚠️ Common mistake: Using dry litmus paper; moisture is required for chlorine gas to dissolve and react.
🧠 Remember: Chlorine bleaches damp litmus paper white!
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